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Compatibility and epitaxial crystallization between Poly(ethylene) and Poly(ethylene)-like polyesters

Pepels, Mark P. F.; Kleijnen, Rob G.; Goossens, Johannes G. P.; Spoelstra, Anne B.; Tandler, Renate; Martens, Hans; Soliman, Maria; Duchateau, Rob

Customer publications

Compatibility and epitaxial crystallization between Poly(ethylene) and Poly(ethylene)-like polyesters

Pepels, Mark P. F.; Kleijnen, Rob G.; Goossens, Johannes G. P.; Spoelstra, Anne B.; Tandler, Renate; Martens, Hans; Soliman, Maria; Duchateau, Rob

This work describes the phase behavior of blends of ‘polyethylene-like’ polypentadecalactone (PPDL) and polyethylene. Blends of high-density polyethylene (HDPE) and PPDL were shown to be immiscible at the onset of crystallization of polyethylene, resulting in phase-separated morphologies. However, epitaxial crystallization of PPDL onto the HDPE crystals was observed by transmission…
Semifluorinated alkanes and alkanes: A phase study of the perfluorohexyloctane – Tetradecane system

Runnsjö, Anna; Kocherbitov, Vitaly; Graf, Gesche; Pettigrew, Anthony; Scherer, Dieter; Mortensen, Kell; Engblom, Johan

Customer publications

Semifluorinated alkanes and alkanes: A phase study of the perfluorohexyloctane – Tetradecane system

Runnsjö, Anna; Kocherbitov, Vitaly; Graf, Gesche; Pettigrew, Anthony; Scherer, Dieter; Mortensen, Kell; Engblom, Johan

The binary system perfluorohexyloctane (F6H8)–tetradecane (C14) was investigated in order to increase understanding of interactions of semifluorinated alkanes (SFAs) with hydrophobic molecules. The thermal phase behavior for F6H8 and C14 and their mixtures was determined using DSC. The activity coefficients for both components in the mixtures were calculated and Gibbs…
Interaction of Artepillin C with model membranes

Pazin, Wallance Moreira; Olivier, Danilo da Silva; Vilanova, Neus; Ramos, Ana Paula; Voets, Ilja Karina; Soares, Ademilson Espencer Egea; Ito, Amando Siuiti

Customer publications

Interaction of Artepillin C with model membranes

Pazin, Wallance Moreira; Olivier, Danilo da Silva; Vilanova, Neus; Ramos, Ana Paula; Voets, Ilja Karina; Soares, Ademilson Espencer Egea; Ito, Amando Siuiti

Green propolis, a mixture of beeswax and resinous compounds processed by Apis mellifera, displays several pharmacological properties. Artepillin C, the major compound in green propolis, consists of two prenylated groups bound to a phenyl group. Several studies have focused on the therapeutic effects of Artepillin C, but there is no…
Nucleation and mechanical enhancements in polyethylene-graphene nanoplate composites

Bourque, Alexander J.; Locker, C. Rebecca; Tsou, Andy H.; Vadlamudi, Madhavi

Customer publications

Nucleation and mechanical enhancements in polyethylene-graphene nanoplate composites

Bourque, Alexander J.; Locker, C. Rebecca; Tsou, Andy H.; Vadlamudi, Madhavi

Graphene nanoplatelets (GNP) dispersed in high-density polyethylene (HDPE) were found to significantly enhance nucleation of PE crystallization, and thermal/mechanical properties of HDPE-GNP nanocomposites. Excellent dispersion of GNPs was achieved by combining solution blending and twin-screw extrusion homogenization. The dispersion state was confirmed by bimodal AFM and also by the resulting…