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Preparation, Structure, and Properties of an Isotactic Polypropylene Film with Ultrahigh Content, Ordered, and Continuous ?-Transcrystallinity

Liang, Guixue; Yang, Shuo; Li, Jiang; Guo, Shaoyun

(Natural) polymersApplicationCharacterizationCustomer publicationsMaterialOrientation analysisPolymer researchSAXSTechniqueTensile

Preparation, Structure, and Properties of an Isotactic Polypropylene Film with Ultrahigh Content, Ordered, and Continuous ?-Transcrystallinity

Liang, Guixue; Yang, Shuo; Li, Jiang; Guo, Shaoyun

?-Transcrystallinity (?-TC) of polypropylene (PP) is a novel kind of crystal that is of significant importance. Owing to the low content, discontinuity, and random distribution of ?-TC obtained by traditional methods, there has not been significant research on this particular crystal. Thus, its formation mechanism and growth law remain unclear…
Moebius strips of chiral block copolymers

Geng, Zhen; Xiong, Bijin; Wang, Liquan; Wang, Ke; Ren, Min; Zhang, Lianbin; Zhu, Jintao; Yang, Zhenzhong

(Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialPolymer researchSelf-assembled materialTechniqueWAXS

Moebius strips of chiral block copolymers

Geng, Zhen; Xiong, Bijin; Wang, Liquan; Wang, Ke; Ren, Min; Zhang, Lianbin; Zhu, Jintao; Yang, Zhenzhong

The Moebius topology (twisted, single-sided strip) is intriguing because of its structural elegance and distinct properties. Here we report the generation of block copolymer Moebius strips via a fast self-assembly of chiral block copolymer polystyrene-block-poly(D-lactide acid) (PS-b-PDLA) in tetrahydrofuran/water mixed solvents. The Moebius strip is formed by morphological evolution from…
Rapid Stabilization of Immiscible Fluids using Nanostructured Interfaces via Surfactant Association

Niroobakhsh, Zahra; LaNasa, Jacob A.; Belmonte, Andrew; Hickey, Robert J.

ApplicationCharacterizationCosmetics & consumer careCustomer publicationsMaterialOil & gasPhase analysisSAXSSurfactantsTechnique

Rapid Stabilization of Immiscible Fluids using Nanostructured Interfaces via Surfactant Association

Niroobakhsh, Zahra; LaNasa, Jacob A.; Belmonte, Andrew; Hickey, Robert J.

Surfactant molecules have been extensively used as emulsifying agents to stabilize immiscible fluids. Droplet stability has been shown to be increased when ordered nanoscale phases form at the interface of the two fluids due to surfactant association. Here, we report on using mixtures of a cationic surfactant and long chained…
Transition Pathway between Gyroid and Cylindrical Morphology in Linear Triblock Terpolymer Thin Films

Guliyeva, Aynur; Vayer, Marylène; Warmont, Fabienne; Takano, Atsushi; Matsushita, Yushu; Sinturel, Christophe

(Natural) polymersApplicationCharacterizationCustomer publicationsGISAXSMaterialPhase analysisPolymer researchSelf-assembled materialSurface structure and patternsTechnique

Transition Pathway between Gyroid and Cylindrical Morphology in Linear Triblock Terpolymer Thin Films

Guliyeva, Aynur; Vayer, Marylène; Warmont, Fabienne; Takano, Atsushi; Matsushita, Yushu; Sinturel, Christophe

A new transition between alternating gyroid (GA) structure and cylindrical morphology was observed in thin films for a poly(isoprene-block-styrene-block-(2-vinylpyridine)) (ISP) triblock terpolymer (I/S/P volume fraction = 0.20:0.66:0.14) exhibiting in bulk a Q214 (space group I4132) morphology. Thin films were organized using solvent vapor annealing (SVA) and characterized by atomic force…
Nanocrystalline ODS-iron aluminide by cryo-milling: consolidation, microstructure and mechanical behavior

Sarma, S. Sudhakara; Prasad, Satya; Joardar, Joydip; Suresh, K.; Reddy, A. V.; Vijay, R.

ApplicationCharacterizationCustomer publicationsInorganic materialsMaterialMetalsSAXSSizeTechnique

Nanocrystalline ODS-iron aluminide by cryo-milling: consolidation, microstructure and mechanical behavior

Sarma, S. Sudhakara; Prasad, Satya; Joardar, Joydip; Suresh, K.; Reddy, A. V.; Vijay, R.

Nanocrystalline oxide dispersion strengthened (ODS) Fe-25 at% Al alloy was produced by cryo-milling of elemental powder blend and Y2O3. The as-milled powder was consolidated by hot extrusion. The Microstructure and mechanical properties of the consolidated material were evaluated. Fracture of powder particles during milling was dominant due to cryo temperatures…
Relation Between Charge Transport and the Number of Interconnected Lamellar Poly(3-Hexylthiophene) Crystals

Wang, Binghua; Chen, Jingbo; Shen, Changyu; Reiter, Günter; Zhang, Bin

(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechnique

Relation Between Charge Transport and the Number of Interconnected Lamellar Poly(3-Hexylthiophene) Crystals

Wang, Binghua; Chen, Jingbo; Shen, Changyu; Reiter, Günter; Zhang, Bin

We have investigated the lateral charge transport in a multilamellar network of crystalline structures of poly(3-hexylthiophene) (P3HT) embedded in a matrix of small crystallites and amorphous polymers resulting from crystallization at temperatures close to the melting point. Removing the matrix by an appropriate washing process allowed us to observe a…