Seitz, Michelle E.; Wiseman, Meredith E.; Hilker, Iris; Loos, Joachim; Tian, Mingwen; Li, Junyu; Goswami, Mithun; Litvinov, Victor M.; Curtin, Scott; Bulters, Markus
Influence of silicone distribution and mobility on the oxygen permeability of model silicone hydrogels
Polymer, 2017, vol 118pp. 150–162DOI:Back to the overview
Rapid and Quantitative De-tert-butylation for Poly(acrylic acid) Block Copolymers and Influence on Relaxation of Thermoassociated Transient Networks
Filippov, Alexei D.; van Hees, Ilse A.; Fokkink, Remco; Voets, Ilja K.; Kamperman, Marleen
The synthesis of charged polymers often requires the polymerization of protected monomers, followed by a polymer-analogous reaction to the polyelectrolyte product. We present a mild, facile method to cleave tert-butyl groups from poly(tert-butyl acrylate) blocks that yields poly(acrylic acid) (pAA) blocks free of traces of the ester. The reaction utilizes…
Progression of the Morphology in Random Ionomers Containing Bulky Ammonium Counterions
Enokida, Joshua S.; Tanna, Vijesh A.; Winter, H. Henning; Coughlin, E. Bryan
Poly(isoprene-ran-dimethyloctylammonium styrenesulfonate) (P(I-ran-DMOASS)) copolymers with high molecular weights and dimethyloctylammonium styrenesulfonate (DMOASS) compositions ranging between 8 and 40 mol % (30 and 77 wt %) were synthesized via nitroxide-mediated polymerization. Thermal and viscoelastic characterization revealed distinct behaviors for the low (30–51 wt %) and high (56–77 wt…