Wang, Hongjian; Chen, Long; Yang, Hao; Wang, Meidi; Yang, Leixin; Du, Haiyan; Cao, Chenliang; Ren, Yanxiong; Wu, Yingzhen; Pan, Fusheng; Jiang, Zhongyi
Brønsted acid mediated covalent organic framework membranes for efficient molecular separation
Covalent organic frameworks (COFs) hold great promise in molecular separation. However, since the aperture size of most COFs is in the range of 0.84.9 nm, constructing COF membranes with a smaller aperture size is thus in urgent demand yet remains a grand challenge. In this study, a Brønsted acid mediated…
Facilitate charge transfer at donor/acceptor interface in bulk heterojunction organic photovoltaics by two-dimensional nanoflakes
Yang, Weitao; Ye, Zhixiang; Liang, Tao; Ye, Jian; Chen, Hongzheng
Recently, two-dimensional (2D) materials have been applied in organic photovoltaics (OPVs) as electrode modifier or third component in bulk due to their high charge carrier mobility, various electronic band structure, and facile fabrication via liquid phase exfoliation. Herein, solution exfoliated few layers black phosphorus (BP) and tungsten diselenide (WSe2) were…
Melt-Spun Nanocomposite Fibers Reinforced with Aligned Tunicate Nanocrystals
Redondo, Alexandre; Chatterjee, Sourav; Brodard, Pierre; Korley, LaShanda T. J.; Weder, Christoph; Gunkel, Ilja; Steiner, Ullrich
The fabrication of nanocomposite films and fibers based on cellulose nanocrystals (P-tCNCs) and a thermoplastic polyurethane (PU) elastomer is reported. High-aspect-ratio P-tCNCs were isolated from tunicates using phosphoric acid hydrolysis, which is a process that affords nanocrystals displaying high thermal stability. Nanocomposites were produced by solvent casting (films) or melt-mixing…
Effects of energy-level offset between a donor and acceptor on the photovoltaic performance of non-fullerene organic solar cells
Yang, Chenyi; Zhang, Jianqi; Liang, Ningning; Yao, Huifeng; Wei, Zhixiang; He, Chang; Yuan, Xiaotao; Hou, Jianhui
Minimizing the energy-level offset between a donor and acceptor in order to reduce energy loss (Eloss) is a hot topic in the field of organic solar cells (OSCs). However, for non-fullerene OSCs, the discussion concerning the relationship between energy-level offset and device performance has not yet reached a general conclusion…
Random Organic Nanolaser Arrays for Cryptographic Primitives
Feng, Jiangang; Wen, Wen; Wei, Xiao; Jiang, Xiangyu; Cao, Moyuan; Wang, Xuedong; Zhang, Xiqi; Jiang, Lei; Wu, Yuchen
Next-generation high-security cryptography and communication call for nondeterministic generation and efficient authentication of unclonable bit sequences. Physical unclonable functions using inherent randomness in material and device fabrication process have emerged as promising candidates for realizing one-way cryptographic systems that avoid duplication and attacks. However, previous
Improvement in mechanical and structural properties of poly(ethylene terephthalate) nanohybrid
Saxena, Dipti; Rana, Dipak; Bhoje Gowd, E.; Maiti, Pralay
The wide range of applicability of poly(ethylene terephthalate) (PET) in various fields such as packaging, automobile parts, sports and textile due to its transparent nature, light weight and mechanical properties creates strong case to enhance its mechanical properties. By embedding nanofillers and thereby improving the mechanical properties, this spectrum can…
Synthesis and Solid-State Properties of PolyC3 (Co)polymers Containing (CH2CH2C(COOR)2) Repeat Units with Densely Packed Fluorocarbon Lateral Chains
Illy, Nicolas; Urayeneza, Deogratias; Maryasevskaya, Alina V.; Michely, Laurent; Boileau, Sylvie; Brissault, Blandine; Bersenev, Egor A.; Anokhin, Denis V.; Ivanov, Dimitri A.; Penelle, Jacques
The synthesis and structural characterization of linear PolyC3 polymers containing trimethylene-1,1-dicarboxylate structural repeat units with C6F13 and C8F17 fluorinated side chains is described for the first time, and their properties were compared with the traditional polyvinyl structures that display the fluorinated chain on every second rather than on every third…
Comparative Study of Direct Compounding, Coupling Agent-Aided and Initiator-Aided Reactive Extrusion to Prepare Cellulose Nanocrystal/PHBV (CNC/PHBV) Nanocomposite
Zheng, Ting; Clemons, Craig M.; Pilla, Srikanth
Three compounding methods were compared to determine their effects on the organization of the interphase in nanocomposites of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and cellulose nanocrystals (CNCs) processed via (1) direct compounding, (2) reactive extrusion using a coupling agent (PHBV-g-GMA), or (3) reactive extrusion using a peroxide free-radical initiator (dicumyl peroxide,
Multi-scale modelling approach to homogenise the mechanical properties of polymeric closed-cell bead foams
Gebhart, Thomas M. J.; Jehnichen, Dieter; Koschichow, Roman; Müller, Michael; Göbel, Michael; Geske, Vinzenz; Stegelmann, Michael; Gude, Maik
The complex mechanical deformation behaviour of closed-cell foams is governed by morphological and physical properties such as cell structure and crystallinity. In this study, the micro-, meso- and macroscopic scale of commercially available bead foam was analysed. Statistical distribution of the cell structure including cell size, wall thickness and shape…
4D biofabrication of skeletal muscle microtissues
Apsite, Indra; Uribe, Juan Manuel; Posada, Andrés Fernando; Rosenfeldt, Sabine; Salehi, Sahar; Ionov, Leonid
Skeletal muscle is one of the most abundant tissues in the body. Although it has a relatively good regeneration capacity, it cannot heal in the case of disease or severe damage. Many current tissue engineering strategies fall short due to the complex structure of skeletal muscle. Biofabrication techniques have emerged…