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Sulfo-Phenylated Polyphenylenes Containing Sterically Hindered Pyridines

Xu, Shaoyi; Adamski, Michael; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialRenewable energySAXSTechnique

Sulfo-Phenylated Polyphenylenes Containing Sterically Hindered Pyridines

Xu, Shaoyi; Adamski, Michael; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven

We systematically investigated the effect of incorporating a sterically hindered pyridyl group into a sulfo-phenylated polyphenylene to control the polymer’s physicochemical properties through acid–base interactions. Homopolymers with similar molecular weights and comparable structures that vary by only one atom (N– vs C?) per repeat unit along the polymer chain were…
Slow Magnetic Relaxation of Co(II) Single Chains Embedded within Metal–Organic Superstructures

Kawamura, Airi; Filatov, Alexander S.; Anderson, John S.; Jeon, Ie-Rang

 (Natural) polymersApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialPhase analysisTechniqueWAXS

Slow Magnetic Relaxation of Co(II) Single Chains Embedded within Metal–Organic Superstructures

Kawamura, Airi; Filatov, Alexander S.; Anderson, John S.; Jeon, Ie-Rang

Two coordination polymers of the type Co(BPDC)(N-ox), with BPDC being 4,4?-biphenyldicarboxylate and N-ox being pyridine N-oxide (PNO) or isoquinoline N-oxide (IQNO), have been synthesized and characterized. The compounds feature 2D and 3D metal–organic networks that encapsulate Co(II)-based chains in a rigid superstructure. The dc and ac magnetic properties of these…
Tuning charge transport dynamics via clustering of doping in organic semiconductor thin films

Boyle, Connor J.; Upadhyaya, Meenakshi; Wang, Peijian; Renna, Lawrence A.; Lu-Díaz, Michael; Jeong, Seung Pyo; Hight-Huf, Nicholas; Korugic-Karasz, Ljiljana; Barnes, Michael D.; Aksamija, Zlatan; Venkataraman, D.

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialRenewable energyTechniqueWAXS

Tuning charge transport dynamics via clustering of doping in organic semiconductor thin films

Boyle, Connor J.; Upadhyaya, Meenakshi; Wang, Peijian; Renna, Lawrence A.; Lu-Díaz, Michael; Jeong, Seung Pyo; Hight-Huf, Nicholas; Korugic-Karasz, Ljiljana; Barnes, Michael D.; Aksamija, Zlatan; Venkataraman, D.

A significant challenge in the rational design of organic thermoelectric materials is to realize simultaneously high electrical conductivity and high induced-voltage in response to a thermal gradient, which is represented by the Seebeck coefficient. Conventional wisdom posits that the polymer alone dictates thermoelectric efficiency. Herein, we show that doping —…
Structural correlations tailor conductive properties in polymerized ionic liquids

Doughty, Benjamin; Genix, Anne-Caroline; Popov, Ivan; Li, Bingrui; Zhao, Sheng; Saito, Tomonori; Lutterman, Daniel A.; Sacci, Robert L.; Sumpter, Bobby G.; Wojnarowska, Zaneta; Bocharova, Vera

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialOtherRenewable energyTechniqueWAXS

Structural correlations tailor conductive properties in polymerized ionic liquids

Doughty, Benjamin; Genix, Anne-Caroline; Popov, Ivan; Li, Bingrui; Zhao, Sheng; Saito, Tomonori; Lutterman, Daniel A.; Sacci, Robert L.; Sumpter, Bobby G.; Wojnarowska, Zaneta; Bocharova, Vera

Polymerized ionic liquids (PolyILs) are promising materials for applications in electrochemical devices spanning from fuel cells to capacitors and batteries. In principle, PolyILs have a competitive advantage over traditional electrolytes in being single ion conductors and thus enabling a transference number close to unity. Despite this perceived advantage, surprisingly low…
Cellular uptake of self-assembled phytantriol-based hexosomes is independent of major endocytic machineries

Rodrigues, Letícia; Schneider, Fabian; Zhang, Xiaohan; Larsson, Elin; Moodie, Lindon W. K.; Dietz, Hendrik; Papadakis, Christine M.; Winter, Gerhard; Lundmark, Richard; Hubert, Madlen

 ApplicationCharacterizationCustomer publicationsLipidsLiquid crystalsMaterialPhase analysisSAXSStructural biologyTechniqueTemperature

Cellular uptake of self-assembled phytantriol-based hexosomes is independent of major endocytic machineries

Rodrigues, Letícia; Schneider, Fabian; Zhang, Xiaohan; Larsson, Elin; Moodie, Lindon W. K.; Dietz, Hendrik; Papadakis, Christine M.; Winter, Gerhard; Lundmark, Richard; Hubert, Madlen

Despite increasing interests in non-lamellar liquid crystalline dispersions, such as hexosomes, for drug delivery, little is known about their interactions with cells and mechanism of cell entry. Here we examine the cellular uptake of hexosomes based on phytantriol and mannide monooleate by HeLa cells using live cell microscopy in comparison…
Morphological Evolution of Poly(solketal methacrylate)-block-polystyrene Copolymers in Thin Films

Yu, Duk Man; Smith, Darren M.; Kim, Hyeyoung; Mapas, Jose Kenneth D.; Rzayev, Javid; Russell, Thomas P.

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGISAXSMaterialOrientation analysisPolymer researchSelf-assembled materialSurface structure and patternsTechniqueThin films

Morphological Evolution of Poly(solketal methacrylate)-block-polystyrene Copolymers in Thin Films

Yu, Duk Man; Smith, Darren M.; Kim, Hyeyoung; Mapas, Jose Kenneth D.; Rzayev, Javid; Russell, Thomas P.

The morphological evolution of the lamellar microdomains in the thin films of symmetric poly(solketal methacrylate-b-styrene) (PSM-b-PS) copolymers that can be converted into poly(glycerol monomethacrylate-b-styrene) (PGM-b-PS) copolymers through acid hydrolysis reaction was investigated. This simple chemical transformation was performed in the solid state using trifluoroacetic acid vapor,…
Microwave-assisted Diels–Alder polycondensation of proton conducting poly(phenylene)s

Adamski, Michael; Skalski, Thomas J. G.; Xu, Shaoyi; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialRenewable energySAXSTechniqueWAXS

Microwave-assisted Diels–Alder polycondensation of proton conducting poly(phenylene)s

Adamski, Michael; Skalski, Thomas J. G.; Xu, Shaoyi; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven

An exploratory microwave-assisted synthesis of a promising proton-conducting, Diels–Alder poly(phenylene) is reported and comprehensively compared against a traditional, thermal polymerization approach. A 24-fold reduction in reaction time is achieved by microwave synthesis. Characterization of polymers prepared by microwave-assisted synthesis vs. the thermal approach reveals little difference in…
Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability

Fan, Jiantao; Willdorf-Cohen, Sapir; Schibli, Eric M.; Paula, Zoe; Li, Wei; Skalski, Thomas J. G.; Sergeenko, Ania Tersakian; Hohenadel, Amelia; Frisken, Barbara J.; Magliocca, Emanuele; Mustain, William E.; Diesendruck, Charles E.; Dekel, Dario R.; Holdcroft, Steven

 (Natural) polymersApplicationCharacterizationCustomer publicationsMaterialRenewable energySAXSShapeSizeTechniqueWAXS

Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability

Fan, Jiantao; Willdorf-Cohen, Sapir; Schibli, Eric M.; Paula, Zoe; Li, Wei; Skalski, Thomas J. G.; Sergeenko, Ania Tersakian; Hohenadel, Amelia; Frisken, Barbara J.; Magliocca, Emanuele; Mustain, William E.; Diesendruck, Charles E.; Dekel, Dario R.; Holdcroft, Steven

The hydroxide anion exchange polymers are key materials of solid polymer electrolyte devices that operate under alkaline conditions. Here the authors show the rational design of such polymers that exhibit high ion exchange capacity and exceptional stability under highly caustic…
Improving Processing, Crystallization, and Performance of Poly-l-lactide with an Amide-Based Organic Compound as Both Plasticizer and Nucleating Agent

Leoné, Nils; Roy, Manta; Saidi, Sarah; de Kort, Gijs; Hermida-Merino, Daniel; Wilsens, Carolus H. R. M.

 (Natural) polymersApplicationCharacterizationCustomer publicationsMaterialOrientation analysisPolymer researchSAXSTechnique

Improving Processing, Crystallization, and Performance of Poly-l-lactide with an Amide-Based Organic Compound as Both Plasticizer and Nucleating Agent

Leoné, Nils; Roy, Manta; Saidi, Sarah; de Kort, Gijs; Hermida-Merino, Daniel; Wilsens, Carolus H. R. M.

In this work, we report on a novel hydrogen-bonding compound, N,N?-bis(2-hydroxyethyl)terephthalamide (BHET), and its potential as additive in poly-l-lactide (PLA). Although the hydroxyl groups of BHET can participate in transesterification with the PLA matrix, we demonstrate through gel permeation chromatography that extrusion at 200 °C does not result in a…
Effect of side chain and backbone length on lamellar spacing in polystyrene-block-poly(dimethyl siloxane) brush block copolymers

Fei, Huafeng; Yavitt, Benjamin M.; Kopanati, Gayathri; Watkins, James J.

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialPolymer researchSAXSSelf-assembled materialTechniqueTemperature

Effect of side chain and backbone length on lamellar spacing in polystyrene-block-poly(dimethyl siloxane) brush block copolymers

Fei, Huafeng; Yavitt, Benjamin M.; Kopanati, Gayathri; Watkins, James J.

We report the synthesis of polystyrene-block-poly(dimethyl siloxane) (PS-b-PDMS) brush block copolymers (BBCPs) through sequential ROMP of norbornene-modified macromonomers (-NB) and explore the effect of side chain length (Nsc) and total backbone degree of polymerization (Nbb) on the self-assembly of lamellar morphologies. Group I (PS-NB Mn = 2.9 kg/mol, PDMS-NB Mn…
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