You, Gexin; Wang, Jiaqi; Wang, Chunyan; Zhou, Xulin; Zhou, Xiuwen; Liu, Lina
Effect of side methyl from mixed diamine chain extenders on microphase separation and morphology of polyurethane fiber
Polyurethane fiber (PUF) can be used as self-adaptive material in the field of nuclear physics and its properties depended on the molecular structure. To explore the effect of side methyl on its degree of microphase separation (DPS) and morphology for PUF, ethanediamine and 1,2-propylene diamine with different molar ratio were…
Impact of Solvent Structuring in Water/tert-Butanol Mixtures on the Assembly of Silica Nanoparticles to Aerogels
Winkler, Robert; Ré, Elisa; Arrachart, Guilhem; Pellet-Rostaing, Stéphane
Soft matter structuring is a useful tool for the preparation of well-structured inorganic materials. Here, we report a strategy using a structured solvent based on binary mixtures as a directing agent for silica nanoparticles in aerogel elaboration. Binary mixtures involving water/ethanol and water/tert-butanol have been respectively chosen as representatives of…
5 nm Ordered Structures Self-Assembled by C2-Symmetric Hybrids with Polyhedral Oligomeric Silsesquioxane and Hexa-peri-Hexabenzocoronene.
Zhang, Wei; Pan, Hongbing; Lyu, Xiaolin; Gu, Kehua; Xiao, Anqi; Shen, Zhihao; Fan, Xing-he
Hybrids consisting of polyhedral oligomeric silsesquioxane (POSS) and hexa-peri-hexabenzocoronene (HBC) with a dumbbell topology and C2 symmetry were designed and synthesized. They self-assemble into 5 nm ordered structures. In particular, the increased steric effect with increasing POSS units stabilizes a square columnar phase (Colsqu) which is important in nanotemplating. These…
Light-induced healing in azobenzene bridged silsesquioxanes
Galante, María J.; Zucchi, Ileana A.; Oyanguren, Patricia A.; Sáiz, Luciana M.
Intrinsic healable polymers are materials capable of repairing itself through its chemical nature, in order to improve stability and durability and to restore the lost functionalities or properties. In this study, azobenzene (AZO) moieties were incorporated into a previously reported bridged silsesquioxane based on the reaction of isocyanatepropyltriethoxysilane (IPTS) with…
How rheological behaviors of concentrated starch affect graft copolymerization of acrylamide and resultant hydrogel
Bao, Xianyang; Yu, Long; Shen, Shirley; Simon, George P.; Liu, Hongsheng; Chen, Ling
Corn starches with different amylose/amylopectin ratios were used to explore the effect of rheological behaviors of concentrated system on the graft copolymerization of acrylamide and resultant hydrogels, which sheds a light on their reactive extrusion process. The viscoelastic moduli of starch melts increased with increasing amylose content (AC), leading to…
A comparison of non-isocyanate and HDI-based poly(ether urethane): Structure and properties
Shen, Ziyun; Zheng, Liuchun; Li, Chuncheng; Liu, Guoming; Xiao, Yaonan; Wu, Shaohua; Liu, Jiajian; Zhang, Bo
DMC-derived poly (ether urethanes) were prepared via isocyanate-free route. The transurethanization reaction of the non-isocyanate route needs higher temperature as compared with the traditional route. There may be some unknown side reactions under high temperature which lead to changes in chemical structure and subsequent thermal and mechanical properties of the…
A printed, recyclable, ultra-strong, and ultra-tough graphite structural material
Zhou, Yubing; Chen, Chaoji; Zhu, Shuze; Sui, Chao; Wang, Chao; Kuang, Yudi; Ray, Upamanyu; Liu, Dapeng; Brozena, Alexandra; Leiste, Ulrich H.; Quispe, Nelson; Guo, Hua; Vellore, Azhar; Bruck, Hugh A.; Martini, Ashlie; Foster, Bob; Lou, Jun; Li, Teng; Hu, Liangbing
The high mechanical performance of common structural materials (e.g., metals, alloys, and ceramics) originates from strong primary bonds (i.e., metallic, covalent, ionic) between constituent atoms. However, the large formation energy of primary bonds requires high temperatures in order to process these materials, resulting in significant manufacturing costs and a substantial…
Effects of Diisocyanate Structure and Disulfide Chain Extender on Hard Segmental Packing and Self-Healing Property of Polyurea Elastomers
Li, Ting; Zheng, Tianze; Han, Jiarui; Liu, Zhanli; Guo, Zhao-Xia; Zhuang, Zhuo; Xu, Jun; Guo, Bao-Hua
Four linear polyurea elastomers synthesized from two different diisocyanates, two different chain extenders and a common aliphatic amine-terminated polyether were used as models to investigate the effects of both diisocyanate structure and aromatic disulfide chain extender on hard segmental packing and self-healing ability. Both direct investigation on hard segments and…
Characterization of poly(butylene succinate)/poly(lactic acid) blends with in-situ sub-micron fibers and intercalation structure manufacturing by volumetric pulsating elongation flow
Tan, Ling-cao; Qu, Jin-ping
In-situ fibrillation and intercalation structure are favoring to improve the properties of polymer blends. In this work poly(butylene succinate)/poly(lactic acid) blends containing such structures have been achieved via volume pulsating elongation flow instead of strong shear. The mechanical properties, crystallization properties and micromorphology of the extruders were well investigated. The…
Room-Temperature Ferromagnetic Sr3YCo4O10+δ and Carbon Black-Reinforced Polyvinylidenefluoride Composites toward High-Performance Electromagnetic Interference Shielding
Lalan, Vidhya; Puthiyedath Narayanan, Aparna; Surendran, Kuzhichalil Peethambharan; Ganesanpotti, Subodh
In this study, we fabricated composites of conducting carbon black (CB), room-temperature ferromagnetic Sr3YCo4O10+δ (SYCO) and polyvinylidenefluoride (PVDF) by the solution mixing and coagulation method for the first time. During the nucleation process of PVDF, the presence of SYCO and CB individually facilitates the crystallization of polar β and semipolar…