Adamski, Michael; Skalski, Thomas J. G.; Xu, Shaoyi; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven
Microwave-assisted DielsAlder polycondensation of proton conducting poly(phenylene)s
An exploratory microwave-assisted synthesis of a promising proton-conducting, DielsAlder poly(phenylene) is reported and comprehensively compared against a traditional, thermal polymerization approach. A 24-fold reduction in reaction time is achieved by microwave synthesis. Characterization of polymers prepared by microwave-assisted synthesis vs. the thermal approach reveals little difference in
Morphological Evolution of Poly(solketal methacrylate)-block-polystyrene Copolymers in Thin Films
Yu, Duk Man; Smith, Darren M.; Kim, Hyeyoung; Mapas, Jose Kenneth D.; Rzayev, Javid; Russell, Thomas P.
The morphological evolution of the lamellar microdomains in the thin films of symmetric poly(solketal methacrylate-b-styrene) (PSM-b-PS) copolymers that can be converted into poly(glycerol monomethacrylate-b-styrene) (PGM-b-PS) copolymers through acid hydrolysis reaction was investigated. This simple chemical transformation was performed in the solid state using trifluoroacetic acid vapor,
Cellular uptake of self-assembled phytantriol-based hexosomes is independent of major endocytic machineries
Rodrigues, Letícia; Schneider, Fabian; Zhang, Xiaohan; Larsson, Elin; Moodie, Lindon W. K.; Dietz, Hendrik; Papadakis, Christine M.; Winter, Gerhard; Lundmark, Richard; Hubert, Madlen
Despite increasing interests in non-lamellar liquid crystalline dispersions, such as hexosomes, for drug delivery, little is known about their interactions with cells and mechanism of cell entry. Here we examine the cellular uptake of hexosomes based on phytantriol and mannide monooleate by HeLa cells using live cell microscopy in comparison…
Structural correlations tailor conductive properties in polymerized ionic liquids
Doughty, Benjamin; Genix, Anne-Caroline; Popov, Ivan; Li, Bingrui; Zhao, Sheng; Saito, Tomonori; Lutterman, Daniel A.; Sacci, Robert L.; Sumpter, Bobby G.; Wojnarowska, Zaneta; Bocharova, Vera
Polymerized ionic liquids (PolyILs) are promising materials for applications in electrochemical devices spanning from fuel cells to capacitors and batteries. In principle, PolyILs have a competitive advantage over traditional electrolytes in being single ion conductors and thus enabling a transference number close to unity. Despite this perceived advantage, surprisingly low…
Tuning charge transport dynamics via clustering of doping in organic semiconductor thin films
Boyle, Connor J.; Upadhyaya, Meenakshi; Wang, Peijian; Renna, Lawrence A.; Lu-Díaz, Michael; Jeong, Seung Pyo; Hight-Huf, Nicholas; Korugic-Karasz, Ljiljana; Barnes, Michael D.; Aksamija, Zlatan; Venkataraman, D.
A significant challenge in the rational design of organic thermoelectric materials is to realize simultaneously high electrical conductivity and high induced-voltage in response to a thermal gradient, which is represented by the Seebeck coefficient. Conventional wisdom posits that the polymer alone dictates thermoelectric efficiency. Herein, we show that doping …
Slow Magnetic Relaxation of Co(II) Single Chains Embedded within MetalOrganic Superstructures
Kawamura, Airi; Filatov, Alexander S.; Anderson, John S.; Jeon, Ie-Rang
Two coordination polymers of the type Co(BPDC)(N-ox), with BPDC being 4,4?-biphenyldicarboxylate and N-ox being pyridine N-oxide (PNO) or isoquinoline N-oxide (IQNO), have been synthesized and characterized. The compounds feature 2D and 3D metalorganic networks that encapsulate Co(II)-based chains in a rigid superstructure. The dc and ac magnetic properties of these…
Sulfo-Phenylated Polyphenylenes Containing Sterically Hindered Pyridines
Xu, Shaoyi; Adamski, Michael; Killer, Miho; Schibli, Eric M.; Frisken, Barbara J.; Holdcroft, Steven
We systematically investigated the effect of incorporating a sterically hindered pyridyl group into a sulfo-phenylated polyphenylene to control the polymers physicochemical properties through acidbase interactions. Homopolymers with similar molecular weights and comparable structures that vary by only one atom (N vs C?) per repeat unit along the polymer chain were…
Effects of artepillin C on model membranes displaying liquid immiscibility
Pazin, W. M.; Vilanova, N.; Voets, I. K.; Soares, A. E. E.; Ito, A. S.
It has been hypothesized that the therapeutic effects of artepillin C, a natural compound derived from Brazilian green propolis, are likely related to its partition in the lipid bilayer component of biological membranes. To test this hypothesis, we investigated the effects of the major compound of green propolis, artepillin C,…
Shape modulation of squaramide-based supramolecular polymer nanoparticles
Talens, Victorio Saez; Makurat, D. M. M.; Liu, Tingxian; Dai, Wei; Guibert, Clément; Noteborn, Willem E. M.; Voets, Ilja K.; Kieltyka, Roxanne E.
We report the synthesis and self-assembly of a library of squaramide-based bolaamphiphiles with variable hydrophobic and hydrophilic domain sizes, consisting of varied aliphatic chains (n = 2 to 12 methylene repeat units) and linear oligo(ethylene glycol) (m = 11 to 36 repeat units), to understand their effect on the formation…
Transparent, Lightweight, and High Strength Polyethylene Films by a Scalable Continuous Extrusion and Solid-State Drawing Process
Lin, Yunyin; Tu, Wei; Verpaalen, Rob C. P.; Zhang, Han; Bastiaansen, Cees W. M.; Peijs, Ton
The continuous production of transparent high strength ultra-drawn high-density polyethylene films or tapes is explored using a cast film extrusion and solid-state drawing line. Two methodologies are explored to achieve such high strength transparent polyethylene films; i) the use of suitable additives like 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (BZT) and ii) solid-state drawing at…