Yue, Bingbing; Yin, Liyuan; Zhao, Wandong; Jia, Xiaoyong; Zhu, Mingjie; Wu, Bin; Wu, Si; Zhu, Liangliang
Chirality Transfer in Coassembled Organogels Enabling Wide-Range Naked-Eye Enantiodifferentiation
Enantiodifferentiation is crucial in organic chemistry, pharmacochemistry, material chemistry, and life science. However, it remains tremendously challenging to achieve a broad enantioselectivity to different types of chiral substrates via a single-material design. Here, we report a coassembled organogel strategy with chirality transfer to make an enantioselective generality possible. This
Preparation and liquid crystal phase properties of discotic cellulose nanoparticles
Li, Chenxi; Evans, Julian; Wang, Nan; Guo, Tingbiao; He, Sailing
Understanding the behavior of fluids with inhomogeneous structural properties is critical for many industrial and biological materials. Sulfuric acid hydrolysis of cotton with ultrasonic treatment and low-speed centrifugation during purification yields spiky discotic cellulose particles. Amorphous cellulose remained in solution and forms discotic units which may be nucleated by crystalline
Improvement of Antialveolar Echinococcosis Efficacy of Albendazole by a Novel Nanocrystalline Formulation with Enhanced Oral Bioavailability
Hu, Chunhui; Liu, Zhengsheng; Liu, Chengyu; Zhang, Yaogang; Fan, Haining; Qian, Feng
Alveolar echinococcosis (AE) is a chronic infectious parasitic disease that is fatal and still being neglected. Currently, the AE treatment recommended by the WHO is complete excision of the lesions, followed by the oral administration of albendazole (ABZ), the only effective first-line anti-AE drug, for two years. Unfortunately, complete excision…
Differential Polymorphic Transformation Behavior of Polybutene-1 with Multiple Isotactic Sequences
Ma, Ya-Ping; Zheng, Wei-Ping; Liu, Chen-Guang; Shao, Hua-Feng; Nie, Hua-Rong; He, Ai-Hua
For the solid-solid transformation from form II to form I of isotactic polybutene-1 (iPB), the temperature dependence of form I nucleation and growth was deemed to control the transformation process. However, the relationship between form I formation and form II disappearance in the transformation process is not clear. In this…
Elaboration of microporous CeO2 thin layers having nanocrystallites network controlled by Pluronic P123: Impact of key experimental parameters
Lu, Zijie; Rébiscoul, Diane; Causse, Jeremy; le Goff, Xavier; Mollard, Nicolas; Deschanels, Xavier
Microporous ceria thin films having nanocrystallites network were synthesized by evaporation-induced self-assembly process, using P123 amphiphilic copolymer as structure-directing agent. The impact of key experimental parameters, i.e., the sol ageing, the relative humidity (RH), the thermal treatment, on the thin layer elaboration were investigated. The results show that the organization…
Influence of hydrogen bonding on the crystallization behavior of poly(ethylene oxide)/ionic liquids mixtures
Li, Wenze; Gong, Pengjian; Huang, Yajiang; Niu, Yanhua; Li, Guangxian
Two types of imidazolium-based ionic liquids (ILs) and and their mixtures were blended with poly(ethylene oxide) (PEO) matrix to tune the strength of intermolecular hydrogen bonding in the system. With the addition of ILs, particularly increasing ratio, significantly reduced overall crystallization kinetics in the order of pure
How Confinement Affects the Nucleation, Crystallization, and Dielectric Relaxation of Poly(butylene succinate) and Poly(butylene adipate) Infiltrated within Nanoporous Alumina Templates
Safari, Maryam; Maiz, Jon; Shi, Guangyu; Juanes, Diana; Liu, Guoming; Wang, Dujin; Mijangos, Carmen; Alegría, Ángel; Müller, Alejandro J.
This work describes the successful melt infiltration of poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA) within 70 nm diameter anodic aluminum oxide (AAO) templates. The infiltrated samples were characterized by SEM, Raman, and FTIR spectroscopy. The crystallization behaviors and crystalline structures of both polymers, bulk and confined, were analyzed by…
Towards mechanical robust yet self-healing polyurethane elastomers via combination of dynamic main chain and dangling quadruple hydrogen bonds
Hu, Jin; Mo, Ruibin; Jiang, Xiang; Sheng, Xinxin; Zhang, Xinya
One of the greatest challenges of robust self-healing materials is the confliction between high chain mobility for self-healing and a stable structure for mechanical strength. Herein, dangling 2-ureido-4-pyrimidione (UPy)-functionalized side groups were introduced into the hard segments of thermoplastic polyurethane (TPU) elastomers, where embedded the dynamic disulfide bonds in the…
Aescin-Induced Conversion of Gel-Phase Lipid Membranes into Bicelle-like Lipid Nanoparticles
Geisler, Ramsia; Pedersen, Martin Cramer; Hannappel, Yvonne; Schweins, Ralf; Prévost, Sylvain; Dattani, Rajeev; Arleth, Lise; Hellweg, Thomas
Mixtures of the phospholipid 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and the saponin ?-aescin spontaneously form monodisperse, bilayered discoidal micelles (also known as bicelles or nanodisks) in aqueous solution. Such bicelles form below the melting temperature of DMPC when the phospholipids are in the rigid L?? state and are precursors of spontaneously formed vesicles.…
Effective corrosion protection by eco-friendly self-healing PMMA-cerium oxide coatings
Harb, Samarah Vargas; Trentin, Andressa; de Souza, Thiago Augusto Carneiro; Magnani, Marina; Pulcinelli, Sandra Helena; Santilli, Celso Valentim; Hammer, Peter
Metallic alloys are extensively used in many technological applications, however their susceptibility to corrosion causes huge economical losses and can result in failure of critical components. Aiming to obtain environmentally friendly, self-healing and high efficient anticorrosive coatings, organic-inorganic hybrids consisting of poly(methyl methacrylate) (PMMA) covalently bonded to CeO2/Ce2O3